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Storage Conditions

The correct method of storing and maintaining chemicals in the laboratory is one of the most important safety points that must be observed in the laboratory due to the potential risks it can bring. If incompatible chemicals are placed next to each other, there is a possibility of their reaction and the production of dangerous products with the ability to catch fire and explode. In addition to causing pollution, improper storage of chemicals can cause wastage of materials and reduce their properties and chemical effects. On the other hand, proper storage of chemicals can be a beneficial way to increase the life and stability of materials. Therefore, in order to prevent the unwanted combination of chemicals with each other and the occurrence of accidents, it is necessary to know the safety tips and their correct storage methods.

Observing the following points can greatly reduce the risks of material incompatibility:

  • Avoid storing acids in the vicinity of bases or active metals such as sodium, potassium and magnesium.
  • Avoid storing solids or oxidizing acids in the vicinity of organic acids and flammable materials.
  • Avoid storing substances that react with water around the sink or near water solutions.
  • Avoid storing acids in the vicinity of materials that produce toxic gases in contact with them (such as sodium cyanide, iron sulfide).
  • Flammable materials should be stored in places completely away from heat.
  • Store materials that can be decomposed by light, away from direct light.

In the table below, the names of some incompatible chemicals whose combination may cause unwanted reactions are given.

Chemical incompatibility list

row

chemical

Incompatible materials

1

acetic acid

Oxidizing agents such as: chromic acid - nitric acid - hydroxyl compounds - ethylene glycol - perchloric acid - peroxides - permanganates

2

Acetone

Nitric acid - sulfuric acid - other oxidizing agents

3

acetylene

chlorine-bromine-copper-fluorine-silver-mercury

4

Alkaline and alkaline earth metals such as aluminum-magnesium-calcium-lithium-sodium-potassium powder

Water - carbon tetrachloride - other chlorinated hydrocarbon compounds - carbon dioxide - halogens

5

Anhydrous ammonia

Mercury (in a mercury barometer) - chlorine - calcium hypochlorite - iodine - bromine - hydrofluoric acid

6

Ammonium nitrate

Acids - metal powder - flammable solutions - chlorates - nitrites - sulfur - fine organic compounds or combustible materials

7

Aniline

Nitric acid - hydrogen peroxide

8

Materials containing arsenic

mitigating factors

9

Azides

Acids

10

Bromine

See factors related to chlorine

11

Calcium oxide

Water

12

Activated carbon

Calcium hypochlorite - other oxidizing agents

13

Chlorates

Ammonium salts - acids - metal powder - sulfur - organic compounds - combustible materials

14

Chlorine

Ammonia - acetylene - butadiene - butane - methane - propane (or other gases obtained from oil) - hydrogen - sodium carbide - benzene - metal powder - turpentine

15

Chlorine dioxide

Ammonia-methane-phosphine-hydrogen sulfide

16

Carmic acid (chromium trioxide)

Acetic acid - naphthalene - camphor - glycerol - alcohol - flammable solutions

17

copper

Acetylene-hydrogen peroxide

18

Cyanides

Acids

19

Flammable solutions

Ammonium nitrate - Chromic acid - Hydrogen peroxide - Nitric acid - Sodium peroxide - Halogens

20

Hydrocarbons (such as: butane-propane-gasoline)

Fluorine-chlorine-bromine-ceramic acid-sodium peroxide-other oxidizing agents

21

Hydrocyanic acid

lye

22

Hydrofluoric acid

Potassium permanganate-sulfuric acid

23

Hydrogen sulfide

Metal oxides - copper powder - oxidizing agents

24

Hypochlorites

Acids - activated carbon - ammonia

25

Iodine

Acetylene - Ammonia (gas or aqueous solution) - Hydrogen

26

mercury

Acetylene-fulminic acid-ammonia

27

Nitrates

Metal and non-metal powders - metal sulfides - combustible solutions

28

nitric acid

Acetic acid - aniline - chromic acid - acid hydrocyanide - hydrogen sulfide - flammable gases and solutions - copper - brass alloy - heavy metals - alkalis

29

Nitrites

Ammonium salts - amides - phosphides - reducing agents

30

Nitroparaffins

Acids-bases-amines-halides

31

Oxalic acid

Silver - chlorites - urea

32

oxygen

Oils - grease - hydrogen - other reducing agents including gases, solutions and flammable solids

33

Perchlorates

Similar to chlorates

34

Perchloric acid

Reducing agents such as: acetic anhydride - bismuth and its alloys - alcohols - paper - wool - grease - oils

35

Phosphorus (white)

Air - oxygen - alkalis - halogens - halogen oxides - oxidizing agents

36

potassium

Carbon tetrachloride - carbon dioxide - water

37

Potassium permanganate

Glycerol - ethylene glycol - benzaldehyde - other reducing agents - sulfuric acid

38

sodium

Carbon tetrachloride - carbon dioxide - water

39

Sodium peroxide

Ethanol-methanol-glacial acetic acid-acetic anhydride-benzaldehyde-carbon disulfide-glycerin-ethylene glycol-acetyl acetate-methylacetate-furfural

40

Sulfides

Acids

41

sulfuric acid

Negates - water - aqueous solutions - reducing agents - chlorates - perchlorates - nitric acid

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